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Hydroalumination of aryldialkynylphosphines RP(CC–tBu)2 (R = Ph, Mes) with equimolar quantities of diethylaluminum hydride afforded mixed alkenyl–alkynyl cyclic dimers in which the dative aluminum–phosphorus bonds are geminal to the exocyclic alkenyl groups. Addition of triethylaluminum to isolated 1 (R = Ph) or to the in situ generated species (R = Mes) caused diethylaluminum ethynide elimination to yield the arylethylphosphorus dimers 2 and 3. These possess a chair-like Al2C2P2 heterocycle with intermolecular Al–P interactions. The boat conformation (4) was obtained by the reaction of tBu–P(CC–tBu)2 with di(tert-butyl)aluminum hydride. Despite being dimeric, 2 behaves as a frustrated Lewis pair and activates small molecules. The reaction with carbon dioxide gave cis/trans isomeric AlPC2O heterocycles that differ only by the configuration of the exocyclic alkenyl unit. Four isomers resulted from the reaction with phenyl isocyanate. This is caused by cis/trans isomerization of the initial CO adduct and subsequent rearrangement to the AlPC2N heterocycle, being the CN adduct.
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