without changing your settings we'll assume you are happy to receive all RSC cookies.
You can change your cookie settings by navigating to our Privacy and Cookies page and following the instructions. These instructions
are also obtainable from the privacy link at the bottom of any RSC page.
We found that the alignments of the alkali cations can be controlled by a distortion of Prussian blue framework; the rubidium ions form a rod structure in a distorted framework of Rb0.85Cu[Fe(CN)6]0.95·1.3H2O, while the cesium ions are isolated dot structures in a non-distorted framework of Cs0.97Cu[Fe(CN)6]0.99·1.1H2O. The Madelung energy calculations revealed that the novel rod structure is stabilized by the alternating rotations of the [Fe(CN)6] units within the three-dimensional coordination polymer framework.
Fetching data from CrossRef. This may take some time to load.