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Issue 8, 2012
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Auxiliary ligand induced structural allomorphism in nanotubular microporous metal–organic frameworks based on discrete magnesium clusters

Hai-Ning Wang,a  Xing Meng,a  Xin-Long Wang,*a  Guang-Sheng Yanga  and  Zhong-Min Su*a 
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* Corresponding authors

a Institute of Functional Material Chemistry, Key Lab of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, People's Republic of China
E-mail: zmsu@nenu.edu.cn, wangxl824@nenu.edu.cn
Tel: (+86)-431-85099108

Abstract

Three allomorphs with the same stoichiometry, [Mg3(H2O)4(5-aip)2(5-Haip)2]·4DMA, were solvothermally synthesized in the presence of different additives and represented the first 8-connected nanotubular networks in Mg-based metal–organic frameworks. The adsorption and delivery of drugs were also determined.

Graphical abstract: Auxiliary ligand induced structural allomorphism in nanotubular microporous metal–organic frameworks based on discrete magnesium clusters

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Publication details

The article was received on 04 Oct 2011, accepted on 30 Nov 2011 and first published on 22 Dec 2011


Article type: Communication
DOI: 10.1039/C2DT11872F
Citation: Dalton Trans., 2012,41, 2231-2233
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    Auxiliary ligand induced structural allomorphism in nanotubular microporous metal–organic frameworks based on discrete magnesium clusters

    H. Wang, X. Meng, X. Wang, G. Yang and Z. Su, Dalton Trans., 2012, 41, 2231
    DOI: 10.1039/C2DT11872F

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