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Issue 32, 2012
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A novel 2D → 3D {Co6PW9}-based framework extended by semi-rigid bis(triazole) ligand

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Abstract

The building blocks {Co6PW9} converging lacunary polyoxometalates and high-nuclear {Co6} clusters are further linked by semi-rigid bis(triazole) ligands to construct a 2D → 3D framework under hydrothermal conditions, [Co63-OH)3(H2O)9L(PW9O34)] (1) (L = 4,4′-bis(1,2,4-triazol-1-ylmethyl)biphenyl).

Graphical abstract: A novel 2D → 3D {Co6PW9}-based framework extended by semi-rigid bis(triazole) ligand

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Publication details

The article was received on 06 Jan 2012, accepted on 20 Apr 2012 and first published on 23 Apr 2012


Article type: Communication
DOI: 10.1039/C2DT00039C
Citation: Dalton Trans., 2012,41, 9587-9589
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    A novel 2D → 3D {Co6PW9}-based framework extended by semi-rigid bis(triazole) ligand

    X. Wang, X. Liu, A. Tian, J. Ying, H. Lin, G. Liu and Q. Gao, Dalton Trans., 2012, 41, 9587
    DOI: 10.1039/C2DT00039C

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