Jump to main content
Jump to site search

Issue 26, 2012
Previous Article Next Article

Synthesis and investigation of the metal–metal interactions in early/late heterobimetallic complexes linking group 5 imido fragments to Co(I)

Author affiliations

Abstract

Phosphinoamide ligands have been utilized to link a CoI center to a Nb or Ta imido fragment. The resulting heterobimetallic complexes, ICo(Ph2PNiPr)3M[double bond, length as m-dash]NtBu, have weakened dative metal–metal interactions as a result of the strongly donating imido ligand. These complexes can be reduced by 2 electrons to generate dinitrogen-bound complexes.

Graphical abstract: Synthesis and investigation of the metal–metal interactions in early/late heterobimetallic complexes linking group 5 imido fragments to Co(i)

Back to tab navigation

Supplementary files

Publication details

The article was received on 05 Jan 2012, accepted on 24 Feb 2012 and first published on 28 Feb 2012


Article type: Paper
DOI: 10.1039/C2DT00034B
Citation: Dalton Trans., 2012,41, 8111-8115
  •   Request permissions

    Synthesis and investigation of the metal–metal interactions in early/late heterobimetallic complexes linking group 5 imido fragments to Co(I)

    D. A. Evers, A. H. Bluestein, B. M. Foxman and C. M. Thomas, Dalton Trans., 2012, 41, 8111
    DOI: 10.1039/C2DT00034B

Search articles by author

Spotlight

Advertisements