Issue 6, 2012
From the journal:

Dalton Transactions

Influence of second sphere hydrogen bonding interaction on a manganese(ii)-aquo complex†

Sanae El Ghachtouli,a   Régis Guillot,a   Pierre Dorlet,bd   Elodie Anxolabéhère-Mallartc  and  Ally Aukauloo*ad  

* Corresponding authors

a Institut de Chimie Moléculaire et des Matériaux d'Orsay, UMR-CNRS 8182, Université de Paris-Sud XI, Orsay, France
E-mail: ally.aukauloo@u-psud.fr
Fax: +33 (0) 169 154 756
Tel: +33 (0) 169 154 755

b Laboratoire Stress Oxydant et Détoxication CNRS URA 2096 F-91191 Gif-sur-Yvette, France and CEA, iBiTec-S, SB2SM, Gif-sur-Yvette, France

c Laboratoire d'Electrochimie Moléculaire UMR 7591 Univ Paris Diderot, Sorbonne Paris Cité, 15 rue Jean-Antoine de Baïf, Paris, Cedex 13, France

d CEA, iBiTec-S, Service de Bioénergétique Biologie Structurale et Mécanismes (SB2SM), CEA, iBiTec-S, SB2SM, Gif-sur-Yvette, France, France

Abstract

We have developed a pentadentate N4O ligand scaffold with a benzimidazole group placed in a rigid fashion to develop hydrogen bonding interaction with the ligand in the sixth position. The mononuclear Mn(II) complex with a water molecule was isolated and characterized. We discuss the role of the outer sphere ligand in stabilising a Mn(II)-aquo complex.

Graphical abstract: Influence of second sphere hydrogen bonding interaction on a manganese(ii)-aquo complex

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Supplementary files

Article information

DOI
https://doi.org/10.1039/C1DT11858G
Article type
Communication
Submitted
01 Oct 2011
Accepted
31 Oct 2011
First published
20 Dec 2011

Dalton Trans., 2012,41, 1675-1677

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Influence of second sphere hydrogen bonding interaction on a manganese(II)-aquo complex

S. E. Ghachtouli, R. Guillot, P. Dorlet, E. Anxolabéhère-Mallart and A. Aukauloo, Dalton Trans., 2012, 41, 1675 DOI: 10.1039/C1DT11858G

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