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Issue 13, 2012
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Silanetriols in the gas phase: single molecules vs. hydrogen-bonded dimers

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Abstract

The first gas phase structure of a silanetriol, tert-butylsilane-triol [tBuSi(OH)3], determined by gas electron diffraction (GED), is reported. Quantum chemical calculations have been performed to elucidate potential intermolecular interactions between silanetriol molecules in the gas phase. The results are set into contrast to solid state structures of tBuSi(OH)3 and related compounds.

Graphical abstract: Silanetriols in the gas phase: single molecules vs. hydrogen-bonded dimers

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Publication details

The article was received on 21 Sep 2011, accepted on 26 Oct 2011 and first published on 17 Nov 2011


Article type: Communication
DOI: 10.1039/C1DT11740H
Citation: Dalton Trans., 2012,41, 3630-3632
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    Silanetriols in the gas phase: single molecules vs. hydrogen-bonded dimers

    S. Spirk, R. J. F. Berger, C. G. Reuter, R. Pietschnig and N. W. Mitzel, Dalton Trans., 2012, 41, 3630
    DOI: 10.1039/C1DT11740H

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