Issue 1, 2012
From the journal:

Catalysis Science & Technology

Synthesis of palladium nanocatalysts with cucurbit[n]uril as both a protecting agent and a support for Suzuki and Heck reactions†

Minna Cao,a   Ye Wei,a   Shuiying Gaoa  and  Rong Cao*a  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the structure of Matter, The Chinese Academy of Science, Fuzhou 350002, China
E-mail: rcao@fjirsm.ac.cn
Fax: +86 59183796710
Tel: +86 59183796710

Abstract

Pd nanocatalysts based on cucurbit[n]uril were successfully synthesized by an operationally simple one-pot liquid-phase method using different reducing agents. Through changing the reducing agents and the ratio of feedstock, well-defined Pd nanostructures with various shapes were obtained. The results of morphological analysis demonstrate that cucurbit[6]uril plays a key role in guiding the formation of Pd nanostructures, and is responsible for the Suzuki and Heck coupling reactions with high efficiency.

Graphical abstract: Synthesis of palladium nanocatalysts with cucurbit[n]uril as both a protecting agent and a support for Suzuki and Heck reactions

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Article information

DOI
https://doi.org/10.1039/C1CY00324K
Article type
Paper
Submitted
17 Aug 2011
Accepted
24 Sep 2011
First published
21 Oct 2011

Catal. Sci. Technol., 2012,2, 156-163

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Synthesis of palladium nanocatalysts with cucurbit[n]uril as both a protecting agent and a support for Suzuki and Heck reactions

M. Cao, Y. Wei, S. Gao and R. Cao, Catal. Sci. Technol., 2012, 2, 156 DOI: 10.1039/C1CY00324K

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