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Issue 5, 2012
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Catalytic epoxidation of styrene and methyl oleate over peroxophosphotungstate entrapped in mesoporous SBA-15

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Abstract

A new route for the heterogenization of peroxophosphotungstate species was developed for the epoxidation of olefins such as styrene and methyl oleate with hydrogen peroxide. The polyoxometalate based catalyst was entrapped inside the pores of a mesoporous SBA-15 support thanks to the grafting of octyl groups at the pores entrance allowing their convenient recycling.

Graphical abstract: Catalytic epoxidation of styrene and methyl oleate over peroxophosphotungstate entrapped in mesoporous SBA-15

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Publication details

The article was received on 13 Feb 2012, accepted on 07 Mar 2012 and first published on 09 Mar 2012


Article type: Communication
DOI: 10.1039/C2CY20082A
Citation: Catal. Sci. Technol., 2012,2, 910-914
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    Catalytic epoxidation of styrene and methyl oleate over peroxophosphotungstate entrapped in mesoporous SBA-15

    E. Poli, R. De Sousa, F. Jérome, Y. Pouilloux and J. Clacens, Catal. Sci. Technol., 2012, 2, 910
    DOI: 10.1039/C2CY20082A

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