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Issue 22, 2012
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Recent advances in paramagnetic-TM-substituted polyoxometalates (TM = Mn, Fe, Co, Ni, Cu)

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Abstract

During the past decade, research into transition-metal-substituted polyoxometalate self-assembly has been greatly developed. This review summarizes the conventional solution syntheses and hydrothermal syntheses of novel substituted polyoxometalates based on the incorporation of paramagnetic transition metals Mn, Fe, Co, Ni, and Cu, with an emphasis on the variety of nuclearities and configurations of encapsulated transition metal cores and the rich architectures of overall polyoxometalates.

Graphical abstract: Recent advances in paramagnetic-TM-substituted polyoxometalates (TM = Mn, Fe, Co, Ni, Cu)

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Publication details

The article was received on 09 Apr 2012 and first published on 04 Sep 2012


Article type: Critical Review
DOI: 10.1039/C2CS35133A
Citation: Chem. Soc. Rev., 2012,41, 7623-7646
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    Recent advances in paramagnetic-TM-substituted polyoxometalates (TM = Mn, Fe, Co, Ni, Cu)

    S. Zheng and G. Yang, Chem. Soc. Rev., 2012, 41, 7623
    DOI: 10.1039/C2CS35133A

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