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The efficient synthesis of enantioenriched compounds is becoming increasingly important in modern organic, pharmaceutical, and materials chemistry. Recently, chiral cooperative bimetallic catalysts have emerged as a powerful tool to achieve high efficiency and selectivity in asymmetric transformations. This tutorial review highlights strategies and recent advances in cooperative bimetallic catalysts which have been developed for a variety of asymmetric transformations.
A tutorial review, with 80 references, of chiral cooperative bimetallic catalysts in asymmetric transformations. Similar to enzyme biocatalysts, these catalytic systems contain multiple metal centers, leading to very high efficiency and selectivity.
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