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Department of Chemistry, National Taiwan University, Taipei 106, Taiwan
E-mail: rsliu@ntu.edu.tw
; Fax: +886-2-33668671
; Tel: +886-2-33661169
b
Institute for Fuel Cell Innovation, National Research Council of Canada, Vancouver, Canada
E-mail: jiujun.zhang@nrc.gc.ca
; Fax: +1 604 221 3001
; Tel: +1 604 221 3087
c
Department of Chemical and Biochemical Engineering, University of British Columbia, Vancouver, Canada
E-mail: dwilkinson@chml.ubc.ca
; Fax: +1 604 221 3019
; Tel: +1 604 221 3019
Chem. Soc. Rev., 2012,41, 5654-5671
DOI:
10.1039/C2CS35019J
Received
19 Jan 2012,
First published online
04 Jul 2012
This review concerns the efficient conversion of sunlight into chemical fuels through the photoelectrochemical splitting of water, which has the potential to generate sustainable hydrogen fuel. In this review, we discuss various photoelectrode materials and relative design strategies with their associated fabrication for solar water splitting. Factors affecting photoelectrochemical performance of these materials and designs are also described. The most recent progress in the research and development of new materials as well as their corresponding photoelectrodes is also summarized in this review. Finally, the research strategies and future directions for water splitting are discussed with recommendations to facilitate the further exploration of new photoelectrode materials and their associated technologies.
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