Issue 9, 2012
From the journal:

Physical Chemistry Chemical Physics

In situ time-resolved DXAFS study of Rh nanoparticle formation mechanism in ethylene glycol at elevated temperature†

Hiroyuki Asakura,a   Kentaro Teramura,a   Tetsuya Shishido,a   Tsunehiro Tanaka,*a   Ning Yan,b   Chaoxian Xiao,c   Siyu Yaoc  and  Yuan Kou*c  

* Corresponding authors

a Kyotodaigaku-katsura, Nishikyo, Kyoto, Japan
E-mail: tanakat@moleng.kyoto-u.ac.jp
Fax: +81 75 383 2561
Tel: +81 75 383 2562

b Institut des Sciences et Ingenierie Chimiques, Ecole Polytechnique Federale de Lausanne (EPFL), Lausanne, Switzerland
E-mail: yan.ning@epfl.ch
Fax: +41 21 693 98 85
Tel: +41 21 693 98 54

c PKU Green Chemistry Centre, Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering, Peking University, Beijing, China
E-mail: yuankou@pku.edu.cn
Fax: +86 10 62751708
Tel: +86 10 62757792

Abstract

A combination of in situ time-resolved DXAFS and ICP-MS techniques reveals that the formation process of Rh nanoparticles (NPs) from rhodium trichloride trihydrate (RhCl3ยท3H2O) in ethylene glycol with polyvinylpyrrolidone (PVP) at elevated temperature is a first-order reaction, which indicates that uniform size Rh NPs appear consecutively and these Rh NPs do not aggregate with each other.

Graphical abstract: In situ time-resolved DXAFS study of Rh nanoparticle formation mechanism in ethylene glycol at elevated temperature

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Article information

DOI
https://doi.org/10.1039/C2CP23070D
Article type
Paper
Submitted
28 Sep 2011
Accepted
05 Dec 2011
First published
27 Jan 2012

Phys. Chem. Chem. Phys., 2012,14, 2983-2990

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In situ time-resolved DXAFS study of Rh nanoparticle formation mechanism in ethylene glycol at elevated temperature

H. Asakura, K. Teramura, T. Shishido, T. Tanaka, N. Yan, C. Xiao, S. Yao and Y. Kou, Phys. Chem. Chem. Phys., 2012, 14, 2983 DOI: 10.1039/C2CP23070D

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