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Issue 20, 2012
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PbS/CdS-sensitized mesoscopic SnO2 solar cells for enhanced infrared light harnessing

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Abstract

Metal oxide semiconductors with lower lying conduction band minimum and superior electron mobility are essential for efficient charge separation and collection in PbS-sensitized solar cells. In the present study, mesoscopic SnO2 was investigated as an alternative photoanode to the commonly used TiO2 and examined comprehensively in PbS-sensitized liquid junction solar cells. To exploit the capability of PbS in an optimized structure, cascaded nPbS/nCdS and alternate n(PbS/CdS) layers deposited by a successive ionic layer adsorption and reaction method were systematically scrutinized. It was observed that the surface of SnO2 has greater affinity to the growth of PbS compared with TiO2, giving rise to much enhanced light absorption. In addition, the deposition of a CdS buffer layer and a ZnS passivation layer before and after a PbS layer was found to be beneficial for efficient charge separation. Under optimized conditions, cascaded PbS/CdS-sensitized SnO2 exhibited an unprecedented photocurrent density of 17.38 mA cm−2 with pronounced infrared light harvesting extending beyond 1100 nm, and a power conversion efficiency of 2.23% under AM 1.5, 1 sun illumination. In comparison, TiO2 cells fabricated under similar conditions showed much inferior performance owing to the less efficient light harnessing of long wavelength photons. We anticipate that the systematic study of PbS-sensitized solar cells utilizing different metal oxide semiconductors as electron transporters would provide useful insights and promote the development of semiconductor-sensitized mesoscopic solar cells employing panchromatic sensitizers.

Graphical abstract: PbS/CdS-sensitized mesoscopic SnO2 solar cells for enhanced infrared light harnessing

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Publication details

The article was received on 22 Feb 2012, accepted on 03 Apr 2012, published on 04 Apr 2012 and first published online on 04 Apr 2012


Article type: Paper
DOI: 10.1039/C2CP40551B
Citation: Phys. Chem. Chem. Phys., 2012,14, 7367-7374
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    PbS/CdS-sensitized mesoscopic SnO2 solar cells for enhanced infrared light harnessing

    Md. A. Hossain, Z. Y. Koh and Q. Wang, Phys. Chem. Chem. Phys., 2012, 14, 7367
    DOI: 10.1039/C2CP40551B

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