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Issue 5, 2012
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Hydrogen bonding of water in 3-methylpyridine studied by O 1s X-ray emission and absorption spectroscopy

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Abstract

O 1s X-ray emission and X-ray absorption spectroscopy is applied to probe hydrogen bonding of water (D2O) in 3-methylpyridine. Owing to element selectivity of X-ray spectroscopies the electronic structure of water in the binary mixture was observed selectively. Based on the observed spectral changes associated with hydrogen bonding in O 1s X-ray emission and X-ray absorption spectra, we have investigated the hydrogen bond of the mixture sample over a wide range of D2O concentrations (XD2O = 0.02–1.0) at room temperature under atmospheric pressure.

Graphical abstract: Hydrogen bonding of water in 3-methylpyridine studied by O 1s X-ray emission and absorption spectroscopy

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Publication details

The article was received on 17 Oct 2011, accepted on 02 Dec 2011 and first published on 06 Dec 2011


Article type: Communication
DOI: 10.1039/C2CP23276F
Citation: Phys. Chem. Chem. Phys., 2012,14, 1576-1580
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    Hydrogen bonding of water in 3-methylpyridine studied by O 1s X-ray emission and absorption spectroscopy

    H. Arai, Y. Horikawa, K. Sadakane, T. Tokushima, Y. Harada, Y. Senba, H. Ohashi, Y. Takata and S. Shin, Phys. Chem. Chem. Phys., 2012, 14, 1576
    DOI: 10.1039/C2CP23276F

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