Issue 11, 2012
From the journal:

CrystEngComm

p-Hydroxybenzoic acid-induced formation of a novel framework based on direct coordination of caesium ions to cucurbit[8]uril†

Kai Chen,a   Li-Li Liang,a   Hang Cong,a   Xin Xiao,a   Yun-Qian Zhang,a   Sai-Feng Xue,a   Qian-Jiang Zhua  and  Zhu Tao*a  

* Corresponding authors

a Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Guizhou University, Guiyang, P. R. China
E-mail: gzutao@263.com

Abstract

A novel three dimensional framework, generated by crystallisation of the ternary mixture of Q[8], CsCl and p-hydroxybenzoic acid (Hyb) has the formula {Cs(H2O)[(Hyb)2@Q[8]]2}+2Hyb·Cl−·24H2O. The crystal structure shows that the 3D framework is constructed from the four Q[8] molecule units through the Hyb-induced coordination of the caesium pair to the portal oxygens of the Q[8]s.

Graphical abstract: p-Hydroxybenzoic acid-induced formation of a novel framework based on direct coordination of caesium ions to cucurbit[8]uril

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Article information

DOI
https://doi.org/10.1039/C2CE06505C
Article type
Communication
Submitted
09 Nov 2011
Accepted
21 Mar 2012
First published
18 Apr 2012

CrystEngComm, 2012,14, 3862-3864

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p-Hydroxybenzoic acid-induced formation of a novel framework based on direct coordination of caesium ions to cucurbit[8]uril

K. Chen, L. Liang, H. Cong, X. Xiao, Y. Zhang, S. Xue, Q. Zhu and Z. Tao, CrystEngComm, 2012, 14, 3862 DOI: 10.1039/C2CE06505C

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