We present the sequential self-assembly of isoreticular bilayer metal–organic frameworks via a pillar insertion route. We also report the construction of a 3D framework from a 2D bilayer framework in an overall three-step self-assembly.
Design and understanding of solid-state and crystalline materials
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Stepwise pillar insertion into metal–organic frameworks: a sequential self-assembly approach
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Department of Chemistry, University of Nebraska-Lincoln, Lincoln, United States
E-mail: chem571@gmail.com ;
Tel: +82-52-217-2546
E-mail: chem571@gmail.com ;
Tel: +82-52-217-2546
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School of Nano-Bioscience and Chemical Engineering, Ulsan National Institute of Science and Technology (UNIST), 50 UNIST Road, Ulsan 689-798, Korea
CrystEngComm, 2012,14, 6129-6131
DOI: 10.1039/C2CE25545F
Received 13 Apr 2012, Accepted 18 May 2012
First published online 03 Jul 2012
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