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Issue 3, 2012
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New symmetrically substituted 1,3,5-triazines as host compounds for channel-type inclusion formation

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Abstract

A new synthetic procedure for the production of symmetrically substituted 1,3,5-triazines by cyclization from aromatic nitriles in the molten state with zinc chloride as a catalyst has been developed and applied for a number of aromatic and fluoro aromatic nitriles. The new triazine 8 [2,4,6-tris(4′-bromobiphenylyl)-1,3,5-triazine] is shown to form channel-type inclusion compounds with several aromatic solvents, featuring two different channels in the same crystal.

Graphical abstract: New symmetrically substituted 1,3,5-triazines as host compounds for channel-type inclusion formation

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Publication details

The article was received on 10 Aug 2011, accepted on 21 Nov 2011 and first published on 08 Dec 2011


Article type: Communication
DOI: 10.1039/C2CE06034E
Citation: CrystEngComm, 2012,14, 768-770
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    New symmetrically substituted 1,3,5-triazines as host compounds for channel-type inclusion formation

    R. Berger, J. Hauser, G. Labat, E. Weber and J. Hulliger, CrystEngComm, 2012, 14, 768
    DOI: 10.1039/C2CE06034E

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