Issue 99, 2012

Nitrosyl isomerism in amorphous Mn(TPP)(NO) solids

Abstract

Reaction of NO with amorphous Mn(TPP) layers gives two Mn(TPP)(NO) isomers with linear and bent Mn–N–O geometries that reversibly interconvert with changes in temperature. DFT computations predict that the linear complex is the singlet ground state while the bent structure is a triplet state.

Graphical abstract: Nitrosyl isomerism in amorphous Mn(TPP)(NO) solids

Supplementary files

Article information

Article type
Communication
Submitted
08 Oct 2012
Accepted
01 Nov 2012
First published
02 Nov 2012

Chem. Commun., 2012,48, 12088-12090

Nitrosyl isomerism in amorphous Mn(TPP)(NO) solids

T. S. Kurtikyan, V. A. Hayrapetyan, G. G. Martirosyan, R. K. Ghazaryan, A. V. Iretskii, H. Zhao, K. Pierloot and P. C. Ford, Chem. Commun., 2012, 48, 12088 DOI: 10.1039/C2CC37337H

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