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Issue 99, 2012
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Bay-substituted perylene bisimide dye with an undistorted planar scaffold and outstanding solid state fluorescence properties

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Abstract

Single crystal X-ray analysis reveals a flat perylene π-scaffold for a perylene bisimide bearing bulky 2,6-diphenylphenoxy substituents at the 1,7 bay positions. The flat structure provides sharp vibronic progressions in the absorption and fluorescence spectra, the sterical shielding outstanding fluorescence quantum yields in the solid state.

Graphical abstract: Bay-substituted perylene bisimide dye with an undistorted planar scaffold and outstanding solid state fluorescence properties

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Publication details

The article was received on 14 Sep 2012, accepted on 12 Oct 2012 and first published on 29 Oct 2012


Article type: Communication
DOI: 10.1039/C2CC36719J
Citation: Chem. Commun., 2012,48, 12050-12052
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    Bay-substituted perylene bisimide dye with an undistorted planar scaffold and outstanding solid state fluorescence properties

    M. Lin, Á. J. Jiménez, C. Burschka and F. Würthner, Chem. Commun., 2012, 48, 12050
    DOI: 10.1039/C2CC36719J

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