Issue 95, 2012
From the journal:

Chemical Communications

Effect of atmosphere on solid-state amine–aldehyde condensations: gas-phase catalysts for solid-state transformations†‡

Dominik Cinčić,*a   Ivana Brekaloa  and  Branko Kaitnera  

* Corresponding authors

a Department of Chemistry, Faculty of Science, University of Zagreb, Horvatovac 102a, HR-10000 Zagreb, Croatia
E-mail: dominik@chem.pmf.hr
Fax: +385 14606341
Tel: +385 14606362

Abstract

The presence of water or organic solvent vapour accelerates the solid-state condensation of solid aromatic amines and aromatic aldehydes into Schiff bases; we show the important role of catalytic triethylamine in the vapour phase in such vapour digestion synthesis, as well as in the liquid phase in synthesis via liquid-assisted grinding.

Graphical abstract: Effect of atmosphere on solid-state amine–aldehyde condensations: gas-phase catalysts for solid-state transformations

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Article information

DOI
https://doi.org/10.1039/C2CC36357G
Article type
Communication
Submitted
31 Aug 2012
Accepted
16 Oct 2012
First published
17 Oct 2012

Chem. Commun., 2012,48, 11683-11685

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Effect of atmosphere on solid-state amine–aldehyde condensations: gas-phase catalysts for solid-state transformations

D. Cinčić, I. Brekalo and B. Kaitner, Chem. Commun., 2012, 48, 11683 DOI: 10.1039/C2CC36357G

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