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Issue 84, 2012
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A silver complex with an N,S,S-macrocyclic ligand bearing an anthracene pendant arm for optical ethylene monitoring

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Abstract

We have synthesised a silver(I) complex with a metal–arene interaction, where the anthracene ring of the ligand sidearm is positioned above the silver(I) ion. The interaction is disrupted by ethylene coordination to the silver(I). The reversible interconversion between the metal–arene and metal–ethylene interactions allowed us to monitor the presence of ethylene.

Graphical abstract: A silver complex with an N,S,S-macrocyclic ligand bearing an anthracene pendant arm for optical ethylene monitoring

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Publication details

The article was received on 21 Jul 2012, accepted on 06 Sep 2012 and first published on 06 Sep 2012


Article type: Communication
DOI: 10.1039/C2CC35277J
Citation: Chem. Commun., 2012,48, 10392-10394
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    A silver complex with an N,S,S-macrocyclic ligand bearing an anthracene pendant arm for optical ethylene monitoring

    Y. Hitomi, T. Nagai and M. Kodera, Chem. Commun., 2012, 48, 10392
    DOI: 10.1039/C2CC35277J

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