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Issue 79, 2012
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Directed assembly of nanoscale Co(II)-substituted {Co9[P2W15]3} and {Co14[P2W15]4} polyoxometalates

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Abstract

Herein we report two structurally intriguing Co(II)-substituted polyoxometalates, a {Co9[P2W15]3} and {Co14[P2W15]4} (compounds 1 and 2) that are formed from the same building blocks under subtly different conditions. Compound 1 displays a structure previously predicted but never before realised, whilst compound 2 is the first Co-containing Dawson-based single-molecule magnet and has a unique cruciform structure.

Graphical abstract: Directed assembly of nanoscale Co(ii)-substituted {Co9[P2W15]3} and {Co14[P2W15]4} polyoxometalates

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Publication details

The article was received on 08 Jul 2012, accepted on 14 Aug 2012 and first published on 30 Aug 2012


Article type: Communication
DOI: 10.1039/C2CC34865A
Citation: Chem. Commun., 2012,48, 9819-9821
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    Directed assembly of nanoscale Co(II)-substituted {Co9[P2W15]3} and {Co14[P2W15]4} polyoxometalates

    C. Lydon, M. M. Sabi, M. D. Symes, D. Long, M. Murrie, S. Yoshii, H. Nojiri and L. Cronin, Chem. Commun., 2012, 48, 9819
    DOI: 10.1039/C2CC34865A

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