Issue 71, 2012
From the journal:

Chemical Communications

Arbuzov chemistry with chlorofullerene C60Cl6: a powerful method for selective synthesis of highly functionalized [60]fullerene derivatives†

Anastasiya A. Yurkova,a   Ekaterina A. Khakina,a   Sergey I. Troyanov,b   Alexander Chernyak,c   Lyubov Shmygleva,a   Alexander S. Peregudov,d   Vyacheslav M. Martynenko,a   Yury A. Dobrovolskiya  and  Pavel A. Troshin*a  

* Corresponding authors

a IPCP RAS, Semenov Prospect 1, Chernogolovka, Russia
E-mail: troshin2003@inbox.ru
Fax: +7 496522-3507
Tel: +7 496522 1418

b Department of Chemistry, Moscow State University, Leninskie gory, Moscow, Russia

c Joint Analytical Center of Scientific Center in Chernogolovka RAS, Russia

d INEOS RAS, Vavylova St. 28, B-334, Moscow, Russia

Abstract

We report Arbuzov-type reactions of chlorofullerene C60Cl6 with trialkyl phosphites producing highly functionalized fullerene derivatives C60[P(O)(OR)2]5H with high yields. The designed family of [60]fullerene phosphonic acids and their esters showed unusual properties which might find valuable material science applications.

Graphical abstract: Arbuzov chemistry with chlorofullerene C60Cl6: a powerful method for selective synthesis of highly functionalized [60]fullerene derivatives

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Article information

DOI
https://doi.org/10.1039/C2CC34338J
Article type
Communication
Submitted
06 May 2012
Accepted
12 Jul 2012
First published
12 Jul 2012

Chem. Commun., 2012,48, 8916-8918

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Arbuzov chemistry with chlorofullerene C60Cl6: a powerful method for selective synthesis of highly functionalized [60]fullerene derivatives

A. A. Yurkova, E. A. Khakina, S. I. Troyanov, A. Chernyak, L. Shmygleva, A. S. Peregudov, V. M. Martynenko, Y. A. Dobrovolskiy and P. A. Troshin, Chem. Commun., 2012, 48, 8916 DOI: 10.1039/C2CC34338J

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