Jump to main content
Jump to site search

Issue 77, 2012
Previous Article Next Article

Carbon disulfide binding at dinuclear and mononuclear nickel complexes ligated by a redox-active ligand: iminopyridine serving as an accumulator of redox equivalents for the activation of heteroallenes

Author affiliations

Abstract

The dinuclear complex Ni2L12-CS2)2 (2), featuring iminopyridine ligation, is prepared by COD substitution from Ni2L1(COD)2 (1). Spectroscopic, structural, and theoretical data reveals significant activation of the metal-bound C–S bonds, as well as the different oxidation states of the iminopyridine in 1 (1−) and 2 (0).

Graphical abstract: Carbon disulfide binding at dinuclear and mononuclear nickel complexes ligated by a redox-active ligand: iminopyridine serving as an accumulator of redox equivalents for the activation of heteroallenes

Back to tab navigation

Supplementary files

Publication details

The article was received on 15 Jun 2012, accepted on 07 Aug 2012 and first published on 08 Aug 2012


Article type: Communication
DOI: 10.1039/C2CC34307J
Citation: Chem. Commun., 2012,48, 9595-9597
  •   Request permissions

    Carbon disulfide binding at dinuclear and mononuclear nickel complexes ligated by a redox-active ligand: iminopyridine serving as an accumulator of redox equivalents for the activation of heteroallenes

    A. Bheemaraju, J. W. Beattie, R. L. Lord, P. D. Martin and S. Groysman, Chem. Commun., 2012, 48, 9595
    DOI: 10.1039/C2CC34307J

Search articles by author

Spotlight

Advertisements