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Issue 69, 2012
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A HYSCORE investigation of bimetallic titanium–vanadium microporous catalysts: elucidating the nature of the active sites

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Abstract

Vanadium and titanium bimetallic AlPO-5 molecular sieves have been synthesized and characterized by means of Electron Spin Echo detected EPR and Hyperfine Sublevel Correlation (HYSCORE) spectroscopy. Direct evidence for framework substitution of redox-active Ti ions and VO2+ units at Al sites is provided through the detection of large 31P hyperfine couplings.

Graphical abstract: A HYSCORE investigation of bimetallic titanium–vanadium microporous catalysts: elucidating the nature of the active sites

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The article was received on 04 Jun 2012, accepted on 06 Jul 2012 and first published on 06 Jul 2012


Article type: Communication
DOI: 10.1039/C2CC33997H
Citation: Chem. Commun., 2012,48, 8700-8702
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    A HYSCORE investigation of bimetallic titanium–vanadium microporous catalysts: elucidating the nature of the active sites

    S. Maurelli, M. Chiesa, E. Giamello, R. M. Leithall and R. Raja, Chem. Commun., 2012, 48, 8700
    DOI: 10.1039/C2CC33997H

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