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Issue 79, 2012
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The selenite-capped polyoxo-4-aurate(III), [AuIII4O4(SeIVO3)4]4−

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The discrete heteropolyaurate [AuIII4O4(SeIVO3)4]4− (Au4Se4) represents only the second member of this class ever reported, and was synthesized via one-pot room temperature condensation in aqueous medium. Au4Se4 was structurally characterized in the solid state and in solution by single-crystal XRD, TGA, FT-IR, 77Se NMR, mass spectrometry and electrochemistry.

Graphical abstract: The selenite-capped polyoxo-4-aurate(iii), [AuIII4O4(SeIVO3)4]4−

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The article was received on 26 May 2012, accepted on 25 Jul 2012 and first published on 02 Aug 2012

Article type: Communication
DOI: 10.1039/C2CC33795A
Citation: Chem. Commun., 2012,48, 9849-9851
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    The selenite-capped polyoxo-4-aurate(III), [AuIII4O4(SeIVO3)4]4−

    Y. Xiang, N. V. Izarova, F. Schinle, O. Hampe, B. Keita and U. Kortz, Chem. Commun., 2012, 48, 9849
    DOI: 10.1039/C2CC33795A

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