Asymmetric olefin aziridination using a newly designed Ru(CO)(salen) complex as the catalyst

Chungsik Kim; Tatsuya Uchida; Tsutomu Katsuki

doi:10.1039/C2CC32997B

Asymmetric olefin aziridination using a newly designed Ru(CO)(salen) complex as the catalyst

Chungsik Kim,^a^b Tatsuya Uchida^a^b and Tsutomu Katsuki*^b

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* Corresponding authors

^a Department of Chemistry, Faculty of Science, Graduate School, Kyushu University, Hakozaki, Japan

^b International Institute for Carbon-Neutral Energy Research (WPI-I2CNER) Kyushu University, Hakozaki, Higashi-ku, Japan
E-mail: katsuscc@chem.kyushu-univ.jp
Fax: +81 92 642 2607

Abstract

Highly enantioselective and good to high-yielding aziridination of conjugated and non-conjugated terminal olefins and cyclic olefins was achieved using a newly designed Ru(CO)(salen) complex as the catalyst in the presence of SESN₃ under mild conditions.

Supplementary files

Publication details

The article was received on 26 Apr 2012, accepted on 24 May 2012 and first published on 24 May 2012

Article type: Communication

DOI: 10.1039/C2CC32997B

Citation: Chem. Commun., 2012,48, 7188-7190

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Asymmetric olefin aziridination using a newly designed Ru(CO)(salen) complex as the catalyst

C. Kim, T. Uchida and T. Katsuki, Chem. Commun., 2012, 48, 7188
DOI: 10.1039/C2CC32997B
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Chemical Communications

Asymmetric olefin aziridination using a newly designed Ru(CO)(salen) complex as the catalyst

Abstract

Supplementary files

Publication details

Asymmetric olefin aziridination using a newly designed Ru(CO)(salen) complex as the catalyst

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