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Issue 47, 2012
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Pd-catalyzed domino carbonylative–decarboxylative allylation: an easy and selective monoallylation of ketones

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Abstract

In the presence of an allyl alcohol, α-chloroacetophenones undergo an allyloxycarbonylation reaction followed by in situ decarboxylative allylation to selectively afford the corresponding monoallylated ketones via a Pd-catalyzed domino sequence. The scope of the reaction was extended to substituted α-chloroacetophenones as well as various allyl alcohols.

Graphical abstract: Pd-catalyzed domino carbonylative–decarboxylative allylation: an easy and selective monoallylation of ketones

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Publication details

The article was received on 02 Apr 2012, accepted on 17 Apr 2012 and first published on 18 Apr 2012


Article type: Communication
DOI: 10.1039/C2CC32391E
Citation: Chem. Commun., 2012,48, 5889-5891
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    Pd-catalyzed domino carbonylative–decarboxylative allylation: an easy and selective monoallylation of ketones

    S. Giboulot, F. Liron, G. Prestat, B. Wahl, M. Sauthier, Y. Castanet, A. Mortreux and G. Poli, Chem. Commun., 2012, 48, 5889
    DOI: 10.1039/C2CC32391E

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