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Issue 48, 2012
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Highly porous and robust ionic MOFs with nia topology constructed by connecting an octahedral ligand and a trigonal prismatic metal cluster

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Abstract

Two non-interpenetrated and isomorphous MOFs with nia topology, cationic JUC-101 and anionic JUC-102, are synthesized by connecting a trigonal prismatic metal cluster with an octahedral organic ligand. JUC-101 obtains a BET surface area of 3742 m2 g−1 and can absorb 4.18 wt% of H2 at 30 atm and 77 K, while JUC-102 can absorb cationic dye molecules and release them under the triggering of ions.

Graphical abstract: Highly porous and robust ionic MOFs with nia topology constructed by connecting an octahedral ligand and a trigonal prismatic metal cluster

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Publication details

The article was received on 01 Apr 2012, accepted on 27 Apr 2012, published on 27 Apr 2012 and first published online on 27 Apr 2012


Article type: Communication
DOI: 10.1039/C2CC32347H
Citation: Chem. Commun., 2012,48, 6010-6012
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    Highly porous and robust ionic MOFs with nia topology constructed by connecting an octahedral ligand and a trigonal prismatic metal cluster

    J. Jia, F. Sun, T. Borjigin, H. Ren, T. Zhang, Z. Bian, L. Gao and G. Zhu, Chem. Commun., 2012, 48, 6010
    DOI: 10.1039/C2CC32347H

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