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Issue 54, 2012
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Exploring the intermediates of photochemical CO2 reduction: reaction of Re(dmb)(CO)3 COOH with CO2

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Abstract

We have investigated the reaction of Re(dmb)(CO)3COOH with CO2 using density functional theory, and propose a mechanism for the production of CO. This mechanism supports the role of Re(dmb)(CO)3COOH as a key intermediate in the formation of CO. Our new experimental work supports the proposed scheme.

Graphical abstract: Exploring the intermediates of photochemical CO2 reduction: reaction of Re(dmb)(CO)3 COOH with CO2

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Publication details

The article was received on 30 Mar 2012, accepted on 12 May 2012 and first published on 17 May 2012


Article type: Communication
DOI: 10.1039/C2CC32288A
Citation: Chem. Commun., 2012,48, 6797-6799
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    Exploring the intermediates of photochemical CO2 reduction: reaction of Re(dmb)(CO)3 COOH with CO2

    J. Agarwal, B. C. Sanders, E. Fujita, H. F. Schaefer III, T. C. Harrop and J. T. Muckerman, Chem. Commun., 2012, 48, 6797
    DOI: 10.1039/C2CC32288A

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