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Issue 46, 2012
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Synthesis of unsymmetrically substituted 2,2′-dihydroxy-1,1′-biaryl derivatives using organic-base-catalyzed Ferrier-type rearrangement as the key step

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Abstract

A strong organic base, TBD, functioned as a unique catalyst for the intramolecular multi-step transformation of lactols using the Ferrier-type rearrangement as the key step to provide unsymmetrically substituted 2,2′-dihydroxy biaryl compounds having four ortho substituents about the biaryl axis without the need for a metal catalyst.

Graphical abstract: Synthesis of unsymmetrically substituted 2,2′-dihydroxy-1,1′-biaryl derivatives using organic-base-catalyzed Ferrier-type rearrangement as the key step

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Publication details

The article was received on 02 Mar 2012, accepted on 16 Apr 2012 and first published on 17 Apr 2012


Article type: Communication
DOI: 10.1039/C2CC31594G
Citation: Chem. Commun., 2012,48, 5781-5783
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    Synthesis of unsymmetrically substituted 2,2′-dihydroxy-1,1′-biaryl derivatives using organic-base-catalyzed Ferrier-type rearrangement as the key step

    M. Terada and K. Dan, Chem. Commun., 2012, 48, 5781
    DOI: 10.1039/C2CC31594G

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