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Issue 46, 2012
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Self-assembly of unprecedented [8 + 12] Cu-metallamacrocycle-based 3D metal–organic frameworks

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Abstract

[8 + 12]-metallamacrocycle-based 3D frameworks {[Cu4(pbt)2(SO4)2(DMF)2(CH3OH)]·7H2O·DMF}n (1) and [12]-macrocycle 3D {[Cu2(pbt)(SO4)(DMSO)(CH3OH)2]·5H2O·CH3OH}n (2) have been obtained. Both complexes display antiferromagnetic couplings and high catalytic activity in the oxidative coupling reaction of 1-ethynylbenzene and oxazolidin-2-one.

Graphical abstract: Self-assembly of unprecedented [8 [ ] + [ ] 12] Cu-metallamacrocycle-based 3D metal–organic frameworks

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Publication details

The article was received on 02 Mar 2012, accepted on 20 Apr 2012 and first published on 23 Apr 2012


Article type: Communication
DOI: 10.1039/C2CC31590D
Citation: Chem. Commun., 2012,48, 5736-5738
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    Self-assembly of unprecedented [8 + 12] Cu-metallamacrocycle-based 3D metal–organic frameworks

    Z. Xu, Q. Wang, H. Li, W. Meng, Y. Han, H. Hou and Y. Fan, Chem. Commun., 2012, 48, 5736
    DOI: 10.1039/C2CC31590D

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