A Mn36Ni4 ‘loop-of-loops-and-supertetrahedra’ aggregate possessing a high ST = 26 ± 1 spin ground state

Maria Charalambous; Eleni E. Moushi; Constantina Papatriantafyllopoulou; Wolfgang Wernsdorfer; Vassilios Nastopoulos; George Christou; Anastasios J. Tasiopoulos

doi:10.1039/C2CC30654A

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

A Mn₃₆Ni₄ ‘loop-of-loops-and-supertetrahedra’ aggregate possessing a high S_T = 26 ± 1 spin ground state†

Maria Charalambous,^a Eleni E. Moushi,^a Constantina Papatriantafyllopoulou,^ab Wolfgang Wernsdorfer,^c Vassilios Nastopoulos,^d George Christou^b and Anastasios J. Tasiopoulos*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, University of Cyprus, 1678 Nicosia, Cyprus
E-mail: atasio@ucy.ac.cy
Fax: +357 22892801
Tel: +357 22892765

^b Department of Chemistry, University of Florida, Gainesville, USA

^c Institut Néel, CNRS, BP-166, Grenoble Cedex 9, France

^d Department of Chemistry, University of Patras, 26500 Patras, Greece

Abstract

The initial use of 1,3-propanediol in mixed Mn/3d cluster chemistry has led to a Mn^III₂₈Mn^II₈Ni^II₄ molecular aggregate which consists of two Mn^III₈Ni₂ loops and two Mn^III₆Mn^II₄ supertetrahedral units and displays a high ground spin state value S_T = 26 ± 1.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C2CC30654A
Article type: Communication
Submitted: 30 Jan 2012
Accepted: 15 Mar 2012
First published: 16 Mar 2012

Download Citation

Chem. Commun., 2012,48, 5410-5412

Permissions

Request permissions

A Mn₃₆Ni₄ ‘loop-of-loops-and-supertetrahedra’ aggregate possessing a high S_T = 26 ± 1 spin ground state

M. Charalambous, E. E. Moushi, C. Papatriantafyllopoulou, W. Wernsdorfer, V. Nastopoulos, G. Christou and A. J. Tasiopoulos, Chem. Commun., 2012, 48, 5410 DOI: 10.1039/C2CC30654A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications