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Issue 44, 2012
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A Mn36Ni4 ‘loop-of-loops-and-supertetrahedra’ aggregate possessing a high ST = 26 ± 1 spin ground state

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Abstract

The initial use of 1,3-propanediol in mixed Mn/3d cluster chemistry has led to a MnIII28MnII8NiII4 molecular aggregate which consists of two MnIII8Ni2 loops and two MnIII6MnII4 supertetrahedral units and displays a high ground spin state value ST = 26 ± 1.

Graphical abstract: A Mn36Ni4 ‘loop-of-loops-and-supertetrahedra’ aggregate possessing a high ST = 26 ± 1 spin ground state

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Publication details

The article was received on 30 Jan 2012, accepted on 15 Mar 2012 and first published on 16 Mar 2012


Article type: Communication
DOI: 10.1039/C2CC30654A
Citation: Chem. Commun., 2012,48, 5410-5412
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    A Mn36Ni4 ‘loop-of-loops-and-supertetrahedra’ aggregate possessing a high ST = 26 ± 1 spin ground state

    M. Charalambous, E. E. Moushi, C. Papatriantafyllopoulou, W. Wernsdorfer, V. Nastopoulos, G. Christou and A. J. Tasiopoulos, Chem. Commun., 2012, 48, 5410
    DOI: 10.1039/C2CC30654A

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