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Issue 48, 2012
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Amplification of enantioselectivity and sensitivity based on non-linear response of molecular wire bearing pseudo-18-crown-6 to chiral amines

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Abstract

Exploiting a non-linear response for chiral discrimination, an intelligent system capable of chirality amplification was designed and constructed as poly(phenyleneethynylene) having chiral pseudo-18-crown-6. Both sensitivity and selectivity were amplified from those limited by the law of mass action.

Graphical abstract: Amplification of enantioselectivity and sensitivity based on non-linear response of molecular wire bearing pseudo-18-crown-6 to chiral amines

  • This article is part of the themed collection: Chirality
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Publication details

The article was received on 18 Jan 2012, accepted on 25 Apr 2012 and first published on 26 Apr 2012


Article type: Communication
DOI: 10.1039/C2CC30417A
Citation: Chem. Commun., 2012,48, 6052-6054
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    Amplification of enantioselectivity and sensitivity based on non-linear response of molecular wire bearing pseudo-18-crown-6 to chiral amines

    K. Hirose, S. Miura, Y. Senda and Y. Tobe, Chem. Commun., 2012, 48, 6052
    DOI: 10.1039/C2CC30417A

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