Metal-free direct oxidative intermolecular diarylation of anilides at ambient temperature assisted by cascade selective formation of C–C and C–N bonds

Rajarshi Samanta; Jonas Lategahn; Andrey P. Antonchick

doi:10.1039/C2CC30324H

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Metal-free direct oxidative intermolecular diarylation of anilides at ambient temperature assisted by cascade selective formation of C–C and C–N bonds

Rajarshi Samanta , Jonas Lategahn and Andrey P. Antonchick

Chem. Commun., 2012, Advance Article

DOI: 10.1039/C2CC30324H
Received 05 Dec 2011, Accepted 25 Jan 2012
First published on the web 25 Jan 2012

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A new atom-economical process of direct oxidative intermolecular functionalization of aniline derivatives by simple arenes was developed. The products were formed in a highly regioselective manner under metal-free conditions at ambient temperature.

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Chemical Communications

Metal-free direct oxidative intermolecular diarylation of anilides at ambient temperature assisted by cascade selective formation of C–C and C–N bonds

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