Issue 24, 2012
From the journal:

Chemical Communications

Multielectron-transfer reactions at single Cu(ii) centers embedded in polyoxotungstates driven by photo-induced metal-to-metal charge transfer from anchored Ce(iii) to framework W(vi)†

Toshihiro Takashima,a   Akira Yamaguchi,a   Kazuhito Hashimoto*ab  and  Ryuhei Nakamura*a  

* Corresponding authors

a Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo, Japan
E-mail: nakamura@light.t.u-tokyo.ac.jp
Fax: +81-3-5452-5748
Tel: +81-3-5452-5748

b ERATO/JST HASHIMOTO Light Energy Conversion Project, 7-3-1 Hongo, Bunkyo-ku, Tokyo, Japan
E-mail: hashimoto@light.t.u-tokyo.ac.jp
Fax: +81-3-5452-5748
Tel: +81-3-5452-5748

Abstract

Using carbon monoxide as a probe molecule for the oxidation state of Cu ions, we demonstrated that anchored polynuclear charge-transfer complexes consisting of CeIII ions and CuII-substituted Keggin-type polyoxotungstates function as efficient visible-light-driven multielectron-transfer catalysts.

Graphical abstract: Multielectron-transfer reactions at single Cu(ii) centers embedded in polyoxotungstates driven by photo-induced metal-to-metal charge transfer from anchored Ce(iii) to framework W(vi)

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Article information

DOI
https://doi.org/10.1039/C2CC17759E
Article type
Communication
Submitted
12 Dec 2011
Accepted
17 Jan 2012
First published
18 Jan 2012

Chem. Commun., 2012,48, 2964-2966

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Multielectron-transfer reactions at single Cu(II) centers embedded in polyoxotungstates driven by photo-induced metal-to-metal charge transfer from anchored Ce(III) to framework W(VI)

T. Takashima, A. Yamaguchi, K. Hashimoto and R. Nakamura, Chem. Commun., 2012, 48, 2964 DOI: 10.1039/C2CC17759E

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