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Issue 24, 2012
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Multielectron-transfer reactions at single Cu(II) centers embedded in polyoxotungstates driven by photo-induced metal-to-metal charge transfer from anchored Ce(III) to framework W(VI)

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Abstract

Using carbon monoxide as a probe molecule for the oxidation state of Cu ions, we demonstrated that anchored polynuclear charge-transfer complexes consisting of CeIII ions and CuII-substituted Keggin-type polyoxotungstates function as efficient visible-light-driven multielectron-transfer catalysts.

Graphical abstract: Multielectron-transfer reactions at single Cu(ii) centers embedded in polyoxotungstates driven by photo-induced metal-to-metal charge transfer from anchored Ce(iii) to framework W(vi)

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Publication details

The article was received on 12 Dec 2011, accepted on 17 Jan 2012 and first published on 18 Jan 2012


Article type: Communication
DOI: 10.1039/C2CC17759E
Citation: Chem. Commun., 2012,48, 2964-2966
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    Multielectron-transfer reactions at single Cu(II) centers embedded in polyoxotungstates driven by photo-induced metal-to-metal charge transfer from anchored Ce(III) to framework W(VI)

    T. Takashima, A. Yamaguchi, K. Hashimoto and R. Nakamura, Chem. Commun., 2012, 48, 2964
    DOI: 10.1039/C2CC17759E

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