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Issue 22, 2012
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Rational addition of capping groups to the phosphomolybdate Keggin anion [PMo12O40]3 by mild, non-aqueous reductive aggregation

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Abstract

Controlled reductive assembly of capped Keggin anions [PMo12O40(MLm)n]3 has been achieved by reduction of [PMo12O40]3 with sodium-mercury amalgam in the presence of metal halides, as exemplified by the rational syntheses of mono-capped [PMo12O40{Co(MeCN)2}]3 and bi-capped [PMo12O40(VO)2]3 and [PMo12O40Sb2]3.

Graphical abstract: Rational addition of capping groups to the phosphomolybdate Keggin anion [PMo12O40]3− by mild, non-aqueous reductive aggregation

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Publication details

The article was received on 07 Dec 2011, accepted on 17 Jan 2012 and first published on 18 Jan 2012


Article type: Communication
DOI: 10.1039/C2CC17670J
Citation: Chem. Commun., 2012,48, 2779-2781
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    Rational addition of capping groups to the phosphomolybdate Keggin anion [PMo12O40]3 by mild, non-aqueous reductive aggregation

    R. Bakri, A. Booth, G. Harle, P. S. Middleton, C. Wills, W. Clegg, R. W. Harrington and R. J. Errington, Chem. Commun., 2012, 48, 2779
    DOI: 10.1039/C2CC17670J

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