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Issue 25, 2012
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A highly reduced cyanogen ligand derived from cyanide reductive coupling

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Abstract

The synthesis, structure, and spectroscopic features of a bimetallic cyanogen complex obtained from the reductive coupling of cyanide by a niobium(IV) precursor are described, and a mechanism for the coupling reaction is proposed based on DFT calculations.

Graphical abstract: A highly reduced cyanogen ligand derived from cyanide reductive coupling

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Publication details

The article was received on 19 Nov 2011, accepted on 21 Jan 2012 and first published on 23 Jan 2012


Article type: Communication
DOI: 10.1039/C2CC17212G
Citation: Chem. Commun., 2012,48, 3061-3063
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    A highly reduced cyanogen ligand derived from cyanide reductive coupling

    A. R. Fox and C. C. Cummins, Chem. Commun., 2012, 48, 3061
    DOI: 10.1039/C2CC17212G

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