Issue 11, 2012
From the journal:

Chemical Communications

A phosphine-free Pd catalyst for the selective double carbonylation of aryl iodides†

Verónica de la Fuente,a   Cyril Godard,a   Ennio Zangrando,b   Carmen Claver*a  and  Sergio Castillón*c  

* Corresponding authors

a Departament de Química Física i Inorgànica, Universitat Rovira i Virgili, C/Marcel.li Domingo s/n, 43007 Tarragona, Spain
E-mail: carmen.claver@urv.cat

b Dipartimento di Scienze Chimiche e Farmaceutiche, via Licio Giorgieri, 1, 34127 Trieste, Italy

c Departament de Química Analítica i Orgànica, Universitat Rovira i Virgili, C/Marcel.li Domingo s/n, 43007 Tarragona, Spain
E-mail: sergio.castillon@urv.cat

Abstract

The first phosphine-free Pd-catalysed double carbonylation of aryl iodides is reported as a general and practical method, giving excellent conversions and selectivities for a wide range of aryl iodides and amine nucleophiles under atmospheric CO pressure.

Graphical abstract: A phosphine-free Pd catalyst for the selective double carbonylation of aryl iodides

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Article information

DOI
https://doi.org/10.1039/C2CC17124D
Article type
Communication
Submitted
16 Nov 2011
Accepted
02 Dec 2011
First published
06 Dec 2011

Chem. Commun., 2012,48, 1695-1697

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A phosphine-free Pd catalyst for the selective double carbonylation of aryl iodides

V. de la Fuente, C. Godard, E. Zangrando, C. Claver and S. Castillón, Chem. Commun., 2012, 48, 1695 DOI: 10.1039/C2CC17124D

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