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Issue 23, 2012
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Tandem post-synthetic modification for functionalized metal–organic frameworks viaepoxidation and subsequent epoxide ring-opening

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Abstract

A sequence of two new post-synthetic modifications, epoxidation using dimethyldioxirane and subsequent epoxide ring-opening, was developed, maintaining the MOF network. A kinetic study shows that the functionalization of metal–organic frameworks with synthetically versatile and reactive oxirane groups is even possible for small pore diameters.

Graphical abstract: Tandem post-synthetic modification for functionalized metal–organic frameworks viaepoxidation and subsequent epoxide ring-opening

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Publication details

The article was received on 09 Nov 2011, accepted on 17 Jan 2012 and first published on 18 Jan 2012


Article type: Communication
DOI: 10.1039/C2CC16949E
Citation: Chem. Commun., 2012,48, 2888-2890
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    Tandem post-synthetic modification for functionalized metal–organic frameworks viaepoxidation and subsequent epoxide ring-opening

    K. Hindelang, S. I. Vagin, C. Anger and B. Rieger, Chem. Commun., 2012, 48, 2888
    DOI: 10.1039/C2CC16949E

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