A self-complexing and self-assembling pillar[5]arene

Nathan L. Strutt; Huacheng Zhang; Marc A. Giesener; Juying Lei; J. Fraser Stoddart

doi:10.1039/C2CC16030G

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Chemical Communications

Issue 11, 2012

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A self-complexing and self-assembling pillar[5]arene

Nathan L. Strutt , Huacheng Zhang , Marc A. Giesener , Juying Lei and J. Fraser Stoddart

Chem. Commun., 2012, 48, 1647-1649

DOI: 10.1039/C2CC16030G
Received 28 Sep 2011, Accepted 29 Nov 2011
First published on the web 20 Dec 2011

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A monofunctionalised pillar[5]arene derivative carrying a viologen side chain which exhibits self-complexation in dilute dichloromethane solutions forms supramolecular daisy chain polymers and eventually organogels as its concentration is increased three-fold over the range from 0.1 to 100 mM.

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Nathan L. Strutt
Huacheng Zhang
Marc A. Giesener
Juying Lei
J. Fraser Stoddart

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Chemical Communications

A self-complexing and self-assembling pillar[5]arene

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