Facile preparation of amine and amino acid adducts of [60]fullerene using chlorofullerene C60Cl6 as a precursor

Alexey B. Kornev; Ekaterina A. Khakina; Sergey I. Troyanov; Alla A. Kushch; Alexander Peregudov; Alexey Vasilchenko; Dmitry G. Deryabin; Vyacheslav M. Martynenko; Pavel A. Troshin

doi:10.1039/C2CC00071G

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Facile preparation of amine and amino acid adducts of [60]fullerene using chlorofullerene C₆₀Cl₆ as a precursor†

Alexey B. Kornev,^a Ekaterina A. Khakina,^a Sergey I. Troyanov,^b Alla A. Kushch,^c Alexander Peregudov,^d Alexey Vasilchenko,^e Dmitry G. Deryabin,^e Vyacheslav M. Martynenko^a and Pavel A. Troshin*^a

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* Corresponding authors

^a IPCP RAS, Semenov Prospect 1, Chernogolovka 141432, Russia
E-mail: troshin2003@inbox.ru
Fax: +7 496515 5420
Tel: +7 496522 1418

^b Department of Chemistry, Moscow State University, Leninskie gory, Moscow 119991, Russia

^c D. I. Ivanovsky Institute of Virology of the Ministry of Health and Social Development of the Russian Federation (IV MHSDRF), Gamaleya str., 16, Moscow 123098, Russia

^d INEOS RAS, Vavylova St. 28, B-334, Moscow 119991, Russia

^e Orenburg State University (OSU), Prospect Pobedy 13, GSP, Orenburg 460018, Russia

Abstract

We report a general synthetic approach to the preparation of highly functionalized amine and amino acid derivatives of [60]fullerene starting from readily available chlorofullerene C₆₀Cl₆. The synthesized water-soluble amino acid derivative of C₆₀ demonstrated pronounced antiviral activity, while the cationic amine-based compound showed strong antibacterial action in vitro.

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DOI: https://doi.org/10.1039/C2CC00071G
Article type: Communication
Submitted: 04 Jan 2012
Accepted: 10 Apr 2012
First published: 11 Apr 2012

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Chem. Commun., 2012,48, 5461-5463

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Facile preparation of amine and amino acid adducts of [60]fullerene using chlorofullerene C₆₀Cl₆ as a precursor

A. B. Kornev, E. A. Khakina, S. I. Troyanov, A. A. Kushch, A. Peregudov, A. Vasilchenko, D. G. Deryabin, V. M. Martynenko and P. A. Troshin, Chem. Commun., 2012, 48, 5461 DOI: 10.1039/C2CC00071G

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