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Issue 10, 2012
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Unsupported d8–d8 interactions in cationic PdII and PtII complexes: evidence for a significant metal–metal bonding character

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Abstract

Isostructural dinuclear Pd and Pt complexes that exhibit unique d8–d8 interactions between dicationic metal centers are reported. These metal–metal interactions are not supported by any bridging ligands and suggest a significant metal–metal bonding character for both Pd and Pt systems.

Graphical abstract: Unsupported d8–d8 interactions in cationic PdII and PtII complexes: evidence for a significant metal–metal bonding character

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Publication details

The article was received on 31 Aug 2011, accepted on 09 Oct 2011 and first published on 25 Oct 2011


Article type: Communication
DOI: 10.1039/C1CC15420F
Citation: Chem. Commun., 2012,48, 1532-1534
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    Unsupported d8–d8 interactions in cationic PdII and PtII complexes: evidence for a significant metal–metal bonding character

    J. Luo, J. R. Khusnutdinova, N. P. Rath and L. M. Mirica, Chem. Commun., 2012, 48, 1532
    DOI: 10.1039/C1CC15420F

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