Issue 10, 2012

Unsupported d8–d8 interactions in cationic PdII and PtII complexes: evidence for a significant metal–metal bonding character

Abstract

Isostructural dinuclear Pd and Pt complexes that exhibit unique d8–d8 interactions between dicationic metal centers are reported. These metal–metal interactions are not supported by any bridging ligands and suggest a significant metal–metal bonding character for both Pd and Pt systems.

Graphical abstract: Unsupported d8–d8 interactions in cationic PdII and PtII complexes: evidence for a significant metal–metal bonding character

Supplementary files

Article information

Article type
Communication
Submitted
31 Aug 2011
Accepted
09 Oct 2011
First published
25 Oct 2011

Chem. Commun., 2012,48, 1532-1534

Unsupported d8–d8 interactions in cationic PdII and PtII complexes: evidence for a significant metal–metal bonding character

J. Luo, J. R. Khusnutdinova, N. P. Rath and L. M. Mirica, Chem. Commun., 2012, 48, 1532 DOI: 10.1039/C1CC15420F

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