Palladium-catalyzed decarboxylative acylation of O-methyl ketoximes with α-keto acids

Minyoung Kim; Jihye Park; Satyasheel Sharma; Aejin Kim; Eonjeong Park; Jong Hwan Kwak; Young Hoon Jung; In Su Kim

doi:10.1039/C2CC38433G

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Palladium-catalyzed decarboxylative acylation of O-methyl ketoximes with α-keto acids

Minyoung Kim,^a Jihye Park,^a Satyasheel Sharma,^a Aejin Kim,^a Eonjeong Park,^a Jong Hwan Kwak,^a Young Hoon Jung^a and In Su Kim*^a

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School of Pharmacy, Sungkyunkwan University, Suwon 440-746, Republic of Korea
E-mail: insukim@skku.edu ;
Fax: +82 31 292 8800 ;
Tel: +82 31 290 7788

Chem. Commun., 2013,49, 925-927

DOI: 10.1039/C2CC38433G
Received 23 Nov 2012, Accepted 03 Dec 2012
First published online 04 Dec 2012

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A mild, practical and efficient palladium-catalyzed decarboxylative ortho-acylation of O-methyl ketoximes with α-keto acids via C–H bond activation is described. In these reactions, a broad range of O-methyl ketoximes and α-keto acids undergoes the decarboxylative cross-coupling reactions with high selectivities and good tolerance.

Abstract from Methods in Organic Synthesis 2013

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Minyoung Kim
Jihye Park
Satyasheel Sharma
Aejin Kim
Eonjeong Park
Jong Hwan Kwak
Young Hoon Jung
In Su Kim

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