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Issue 10, 2013
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A reagentless thermal post-synthetic rearrangement of an allyloxy-tagged metal–organic framework

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Abstract

Direct heating of a metal–organic framework provides a simple, controllable way of effecting a covalent post-synthetic modification. Herein we report that an allyloxy-tagged zinc metal–organic framework undergoes a thermally-promoted aromatic Claisen rearrangement through which the framework connectivity and porosity are maintained.

Graphical abstract: A reagentless thermal post-synthetic rearrangement of an allyloxy-tagged metal–organic framework

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Publication details

The article was received on 13 Nov 2012, accepted on 14 Dec 2012 and first published on 17 Dec 2012


Article type: Communication
DOI: 10.1039/C2CC38176A
Citation: Chem. Commun., 2013,49, 990-992
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    A reagentless thermal post-synthetic rearrangement of an allyloxy-tagged metal–organic framework

    A. D. Burrows, S. O. Hunter, M. F. Mahon and C. Richardson, Chem. Commun., 2013, 49, 990
    DOI: 10.1039/C2CC38176A

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