Tandem ammonia borane dehydrogenation/alkene hydrogenation mediated by [Pd(NHC)(PR3)] (NHC = N-heterocyclic carbene) catalysts

Caroline E. Hartmann; Václav Jurčík; Olivier Songis; Catherine S. J. Cazin

doi:10.1039/C2CC38145A

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Tandem ammonia borane dehydrogenation/alkene hydrogenation mediated by [Pd(NHC)(PR₃)] (NHC = N-heterocyclic carbene) catalysts†

Caroline E. Hartmann,^a Václav Jurčík,^ab Olivier Songis^b and Catherine S. J. Cazin*^ab

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* Corresponding authors

^a Institute of Chemical Research of Catalonia (ICIQ), Av. Països Catalans 16, 43007 Tarragona, Spain

^b EaStCHEM School of Chemistry, University of St Andrews, St Andrews, UK
E-mail: cc111@st-andrews.ac.uk
Fax: +44 (0)1334 463808

Abstract

[Pd(NHC)(PR₃)] complexes were shown to be active catalysts in the dehydrogenation of ammonia borane and the subsequent hydrogenation of unsaturated compounds at very low catalyst loadings (0.05 mol% for some substrates).

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Article information

DOI: https://doi.org/10.1039/C2CC38145A
Article type: Communication
Submitted: 11 Nov 2012
Accepted: 12 Dec 2012
First published: 14 Dec 2012

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Chem. Commun., 2013,49, 1005-1007

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Tandem ammonia borane dehydrogenation/alkene hydrogenation mediated by [Pd(NHC)(PR₃)] (NHC = N-heterocyclic carbene) catalysts

C. E. Hartmann, V. Jurčík, O. Songis and C. S. J. Cazin, Chem. Commun., 2013, 49, 1005 DOI: 10.1039/C2CC38145A

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