Synthesis, breathing, and gas sorption study of the first isoreticular mixed-linker phosphonate based metal–organic frameworks

Marco Taddei; Ferdinando Costantino; Andrea Ienco; Angiolina Comotti; Phuong V. Dau; Seth M. Cohen

doi:10.1039/C2CC38092G

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Chemical Communications

Issue 13, 2013

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Synthesis, breathing, and gas sorption study of the first isoreticular mixed-linker phosphonate based metal–organic frameworks

Marco Taddei,^a Ferdinando Costantino,*^a^b Andrea Ienco,^b Angiolina Comotti,^c Phuong V. Dau^d and Seth M. Cohen^d

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Dipartimento di Chimica, University of Perugia, Via Elce di Sotto 8, Perugia, Italy
E-mail: fcost@unipg.it

CNR – ICCOM, Via Madonna del Piano 10, Sesto Fiorentino, Italy

Department of Materials Science, University of Milano Bicocca, via, R. Cozzi, Milan, Italy

Department of Chemistry and Biochemistry, University of California, San Diego, 9500 Gilman Drive, La Jolla, USA

Chem. Commun., 2013,49, 1315-1317

DOI: 10.1039/C2CC38092G
Received 08 Nov 2012, Accepted 21 Dec 2012
First published online 21 Dec 2012

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The synthesis of the first water stable isoreticular phosphonate based mixed-linker metal–organic frameworks (MOFs) is achieved via the use of the N-donor heterocyclic co-ligands. Furthermore, these isoreticular phosphonate frameworks show selective CO₂/N₂ uptake at low pressures.

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Marco Taddei
Ferdinando Costantino
Andrea Ienco
Angiolina Comotti
Phuong V. Dau
Seth M. Cohen

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Chemical Communications

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