Activation of dichloromethane by a V(III) thiolate complex: an example of S-based nucleophilic reactivity in an early transition metal thiolate

Tzu-Tso Chen; Yu-Sen Chen; Ya-Ho Chang; Jung-Ching Wang; Yi-Fang Tsai; Gene-Hsiang Lee; Tin-Shen Kuo; Hua-Fen Hsu

doi:10.1039/C2CC37801A

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Chemical Communications

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Activation of dichloromethane by a V(III) thiolate complex: an example of S-based nucleophilic reactivity in an early transition metal thiolate

Tzu-Tso Chen,^a Yu-Sen Chen,^a Ya-Ho Chang,^a Jung-Ching Wang,^a Yi-Fang Tsai,^a Gene-Hsiang Lee,^b Tin-Shen Kuo^c and Hua-Fen Hsu*^a

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Department of Chemistry, National Cheng Kung University, Tainan 701, Taiwan
E-mail: konopka@mail.ncku.edu.tw ;
Fax: +886-62740552 ;
Tel: +886-62757575-65336

Department of Chemistry, National Taiwan University, Taipei 116, Taiwan

Department of Chemistry, National Taiwan Normal University, Taipei 116, Taiwan

Chem. Commun., 2013,49, 1109-1111

DOI: 10.1039/C2CC37801A
Received 27 Oct 2012, Accepted 17 Dec 2012
First published online 17 Dec 2012

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A V^III thiolate complex activated C–Cl bond in dichloromethane via S-based nucleophilic attack. The reaction products, a V^III-Cl species (major one) and a V^IV binding to a CH₂ containing ligand (minor one) were obtained. The work demonstrates sulfur donors in the early-transition metal thiolates having strong nucleophilic characteristics.

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Tzu-Tso Chen
Yu-Sen Chen
Ya-Ho Chang
Jung-Ching Wang
Yi-Fang Tsai
Gene-Hsiang Lee
Tin-Shen Kuo
Hua-Fen Hsu

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Chemical Communications

Activation of dichloromethane by a V(III) thiolate complex: an example of S-based nucleophilic reactivity in an early transition metal thiolate

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Activation of dichloromethane by a V(III) thiolate complex: an example of S-based nucleophilic reactivity in an early transition metal thiolate

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