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Issue 5, 2013
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Ruthenium-catalyzed highly regio- and stereoselective hydroarylation of aryl carbamates with alkynes via C–H bond activation

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Abstract

Chelation-assisted alkenylation of ortho C–H bond of aryl carbamates with alkynes in the presence of a ruthenium catalyst, AgSbF6 and pivalic acid gives highly substituted alkene derivatives in good to excellent yields in a highly regio- and stereoselective manner.

Graphical abstract: Ruthenium-catalyzed highly regio- and stereoselective hydroarylation of aryl carbamates with alkynes via C–H bond activation

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Publication details

The article was received on 01 Oct 2012, accepted on 07 Nov 2012 and first published on 08 Nov 2012


Article type: Communication
DOI: 10.1039/C2CC37758F
Citation: Chem. Commun., 2013,49, 481-483
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    Ruthenium-catalyzed highly regio- and stereoselective hydroarylation of aryl carbamates with alkynes via C–H bond activation

    M. C. Reddy and M. Jeganmohan, Chem. Commun., 2013, 49, 481
    DOI: 10.1039/C2CC37758F

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